 Professor Sylvain Jugé Pr. Sylvain Jugé, was born in Aulnay sous Bois (Seine St Denis), August 30th 1949. French nationality - Married, 4 children. Email address: This e-mail address is being protected from spambots. You need JavaScript enabled to view it Diploma: 1972: Master of Organic-Physical Chemistry (Université d’Orsay); 1975- PhD (Université d’ Orsay)- Pr. H. Kagan; Stereochemical studies in sulfoxide series. Asymmetric induction during energy transfers; 1984- Habilitation: New asymmetric synthesis of phosphinates and phosphine oxides. 1985: Postdoctoral fellow- Université P.& M. Curie, Paris- Pr. J.P. Genêt: Pd-catalyzed asymmetric allylic reactions. Teaching positions: Lecturer at the Université de Paris Sud/Orsay, then at the "Conservatoire National des Arts et Métiers" (1974-76). Senior lecturer at the "Conservatoire National des Arts et Métiers", then at the "École Nationale Supérieure de Chimie de Paris" (1987-91). Professor at the Université de Cergy-Pontoise (1991-2001). Since 2001: Professor at the Université de Bourgogne Manager positions: Head of the "Specific Reactivity" group (EA 1389) at the Université de Cergy Pontoise (1992-98); Member of the board, founder and director of the chemistry department of the Université de Cergy Pontoise (1991-97); Member of the board of the French Chemical Society (2003-07); Expert at the Ministry of Research and Technology; Regional chair of the "Bourgogne-Franche-Comté" French Chemical Society (2003-). Head of the Stereochemistry and Organometallic Complexes group at the Institute of Molecular Chemistry of the Université de Bourgogne (ICMUB, UMR CNRS 5260); Head of the Chemical Department of the Université de Bourgogne (2007-09). Chair the chemistry proposal board (2008-to date). Honour: Decoration from the Ministry of Education (1999); 4 communication prizes Scientific diffusion: Chairman of the GECOM-CONCOORD 1997- Royaumont Abbey. Member of the organizing committee for OMCOS 10 (Versailles 1999). Invited editor of the Journal of Organometallic Chemistry vol 567, 1998. Reading and preface of the french edition of the "Fundamental Organic Chemistry" J. McMurry. Referee to JACS, JOC, Org. Lett., Inorg. Chem., Acc. Chem. Res., Chem. Coord. Rev., JOMC, Tetrahedron, Tet. Asym., Tet. Lett., New J. Chem. Synlett., Bioorg.& Med.Chem., J. Mol. Cat. A., Adv. Synth.& Cat., Chem. to Day. Participation to 86 PhD examination committees and 8 habilitations. Fields of interest: Phosphorus chemistry; Asymmetric synthesis and catalysis. Organometallic chemistry. Research funds: Ministry of Research; CNRS; Bourgogne Country Council; ELF Aquitaine (1981-91). Hoechst (1997-00). Synthelor (2002-09). PAI Galilée 2006. ANR free MetChirPhos 2007-. Direction of Master, PhD and post-docs: 18 masters; 20 PhD directions including three co-directions with the Universities of Firenze (Italy) and Sherbrooke (Canada); 3 post-docs. Published work: h-index: 20; average of citation: 23; 80 publications, 1 chapter of book; 2 prefaces; 73 invited lectures in national and international congresses, academic or industrial centers; 153 communications including 40 oral; 14 patents including 12 international; 7 sealed envelopes. Selected recent publications [a] Highly enantiomerically enriched chlorophosphines boranes: synthesis and applications as P-chirogenic electrophilic blocks C. Bauduin, D. Moulin, El Bachir Kaloun, C. Darcel, S. Jugé J. Org. Chem. 2003, 11, 4293-4301. [b] Efficient synthesis of β-halogeno protected L-alanines and their β-phosphonium derivatives F. Meyer, A. Laaziri, A.M. Papini, J. Uziel, S. Jugé Tetrahedron: Asymmetry 2003, 14, 2229-2238.[c] A novel phosphorus-carbon bond formation by ring opening with diethyl phosphite of oxazolines derived from serine F. Meyer, A. Laaziri, A.M. Papini, J. Uziel, S. Jugé Tetrahedron 2004, 60, 3593-3597. [d] A P-chirogenic β-aminophosphine synthesis by diastereoselective reaction of the α-metalated PAMP- borane complex with benzaldimine J.M. Camus, J. Andrieu, P. Richard, R. Poli, C. Darcel, S. Jugé Tetrahedron: Asymmetry 2004, 15, 2061-2065. [e] Enantio-differentiation of acyclic phosphonium salts in chiral liquid crystalline solutions A.Meddour, J. Uziel, J. Courtieu, S. Jugé Tetrahedron : Asymmetry 2006, 17, 1424-1429. [f] Modular P-chirogenic amino-phosphine-phosphinite ligands for Rh-catalyzed asymmetric hydrogenation: A new model for predicting the enantioselectivity. C. Darcel, D. Moulin, J.C. Henry, M. Lagrelette, P. Richard, P. Harvey, S. Jugé, Eur. J. Org. Chem. 2007, 13, 2078-2090. [g] Enantioselective synthesis of P-chirogenic phosphorus compounds via the ephedrine-borane. Complex methodology S. Jugé Phosphorus, Sulfur and Silicon & Related Compounds 2008, 183(2-3); 233- 248. [h] Synthesis of P-stereogenic phosphorus compounds based on chiral aminoalcohols as chiral auxiliary C. Darcel, J. Uziel, S. Jugé in Phosphorus Ligands in Asymmetric Catalysis Synthesis and Applications, A. Börner (ed.), 2008, Wiley-VCH. [i] Ferrocenyl glyco-peptides as electrochemical probes to detect autoantibodies in multiple sclerosis patients’ sera F.R. Fernández, A. Colson, J. Bayardon, F. Nuti, E. Peroni, R.Meunier-Prest, F.Lolli, M.Chelli, C.Darcel, S. Jugé, A.M. Papini, Biopolymers 2008 , 90(4), 488- 495. [j] The First C3- ymmetric P-Stereogenic Diphosphinomethane Trinuclear Palladium Clusters:Synthesis and Characterization. C. Salomon, D. Fortin, C. Darcel, S. Jugé, P. D. Harvey, J. Clust. Sci. 2009,20(2), 267. |
